Development and research of nanopores
intermetallic
hydrogen storages.
hydrogen storages.
One of the integral components of all
cycle of generating of the electric power with use of hydrogen is its
accumulation in corresponding capacities directly for use in fuel cells. With
reference to fuel cells for vehicles it means creation of compact capacities
from materials which structure would allow to absorb operatively hydrogen in
lots, to keep it at room temperatures and by doses to release it. Known
materials for today do not possess necessary minimal capacity and have the
raised temperature hydrogen desorption.
Listed above conditions define criteria of
a choice of materials for capacities - they should possess the developed
internal porosity with the greatest possible area of a surface. The material of
which they will be made, should be steady in relation to oxides of carbon and
the area of an internal surface should not change in the established
temperature interval (<100oC). In the best way to all these
requirements satisfy with special image created composite intermetallic nanocrystalline
structures possessing well
developed nanopores ensemble. Nanopores in this ensemble must be connected each
other by channel systems. Presence of channels is an obligatory condition
for downturn of temperature hydrogen desorption.
In the National Science Centre “Kharkov Institute
of Physics & Technology” (Kharkov, Ukraine) carried out researches on nanopores
structures creation. The certain results are received. It has been established,
that ion beam-assisted deposition technology, which connects two processes – metals
vapor deposition and simultaneous
bombardment by gas ions with energy some tens keV, can be used not only for
creation of dense and wear protected coatings,
but also for formation of structures with the set level of internal porosity. These
materials are stabile during the annealing at 500оС.
In the given direction there is an
opportunity to create the breadboard models of fuel cells by association nanopores
coatings with nanocrystalline and possessing good hydrogen permeation
intermetallic materials.
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